Lewis structure of PCl₃
26 valence electrons. Three P-Cl single bonds, with one lone pair on P.
Lewis structure
26 valence electronsFormal charges: none
Why this shape
- P has 5 valence electrons. It uses three in three single bonds to Cl, so two are left as one lone pair.
- Steric number = three sigma bonds + one lone pair = 4, so P is sp³ hybridised.
- Four electron pairs point to the corners of a tetrahedron (tetrahedral electron geometry). With one lone pair in place of atoms, the atoms make a trigonal pyramidal shape.
- Repulsion falls in the order lone pair to lone pair > lone pair to bond pair > bond pair to bond pair. The lone pair pushes the bond pairs closer, so the angle is about 100°, less than the ideal 109.5°.
- The bond dipoles do not cancel in the trigonal pyramidal shape, so PCl₃ is polar.
How to draw it
- Count the valence electrons: P 5 + 3 × Cl 7 = 26 valence electrons, 13 pairs.
- Put P in the middle and join it to the three outer atoms with single bonds.
- Give each outer atom lone pairs until it has an octet (H needs only two electrons), then put any electrons left over on the central atom.
- Result: three P-Cl single bonds, with one lone pair on P.
- Formal charge = valence electrons − lone pair electrons − number of bonds. Here: none.
Class 11, Chapter 4 Chemical Bonding and Molecular Structure.
Lewis structure of PCl3: quick answers
How many valence electrons are in PCl3?
P 5 + 3 × Cl 7 = 26 valence electrons, 13 pairs.
What are the formal charges in the Lewis structure of PCl3?
Every atom has a formal charge of zero.
How many lone pairs are in the Lewis structure of PCl3?
10 in all, 1 of them on the central P.