Numford
Balanced in acidic solution

Zn and HCl

Zn + 2HCl → ZnCl₂ + H₂

Redox balancer

Type the reactants and products with an arrow, without numbers: MnO4- + Fe2+ -> Mn2+ + Fe3+. Leave out H+, OH- and water; they are added for you. Salts and acids such as KMnO4 or HNO3 are fine.

Zn+2HCl→ZnCl₂+H₂

Ionic Zn+2H⁺→Zn²⁺+H₂

  • Oxidising agentH⁺
  • Reducing agentZn
  • Electrons2

OxidationZn 0 → +2

Zn→Zn²⁺+2e⁻

loses 2 e⁻

ReductionH +1 → 0

2H⁺+2e⁻→H₂

gains 2 e⁻
  1. Write the skeleton in ionic form
    Zn + H⁺ → Zn²⁺ + H₂
    Written as ions: HCl as H⁺ + Cl⁻; ZnCl₂ as Zn²⁺ + 2Cl⁻.
    Cl⁻ does not change and is left out.
  2. Split into two half reactions
    Oxidation: Zn → Zn²⁺ (Zn 0 → +2)
    Reduction: H⁺ → H₂ (H +1 → 0)
  3. Balance atoms other than O and H
    Oxidation: Zn → Zn²⁺
    Reduction: 2H⁺ → H₂
  4. Balance the charge with electrons
    Oxidation: Zn → Zn²⁺ + 2e⁻
    Reduction: 2H⁺ + 2e⁻ → H₂
  5. The electrons are already equal
    Oxidation: Zn → Zn²⁺ + 2e⁻
    Reduction: 2H⁺ + 2e⁻ → H₂
  6. Add the halves and cancel what appears on both sides
    Zn + 2H⁺ → Zn²⁺ + H₂
  7. Check
    Each side has 1 Zn, 2 H and a total charge of +2.
  8. Put back the ions that do not change
    Zn + 2HCl → ZnCl₂ + H₂
Both methods

Step by step

Ion-electron method

  1. Write the skeleton in ionic form
    Zn + H⁺ → Zn²⁺ + H₂
    Written as ions: HCl as H⁺ + Cl⁻; ZnCl₂ as Zn²⁺ + 2Cl⁻.
    Cl⁻ does not change and is left out.
  2. Split into two half reactions
    Oxidation: Zn → Zn²⁺ (Zn 0 → +2)
    Reduction: H⁺ → H₂ (H +1 → 0)
  3. Balance atoms other than O and H
    Oxidation: Zn → Zn²⁺
    Reduction: 2H⁺ → H₂
  4. Balance the charge with electrons
    Oxidation: Zn → Zn²⁺ + 2e⁻
    Reduction: 2H⁺ + 2e⁻ → H₂
  5. The electrons are already equal
    Oxidation: Zn → Zn²⁺ + 2e⁻
    Reduction: 2H⁺ + 2e⁻ → H₂
  6. Add the halves and cancel what appears on both sides
    Zn + 2H⁺ → Zn²⁺ + H₂
  7. Check
    Each side has 1 Zn, 2 H and a total charge of +2.
  8. Put back the ions that do not change
    Zn + 2HCl → ZnCl₂ + H₂

Oxidation number method

  1. Write the oxidation numbers and find the change
    Zn: 0 in Zn → +2 in Zn²⁺, a rise of 2 for Zn → Zn²⁺ (oxidation)
    H: +1 in H⁺ → 0 in H₂, a fall of 2 for 2H⁺ → H₂ (reduction)
  2. Make the total rise equal the total fall (2 each)
    Zn + 2H⁺ → Zn²⁺ + H₂
  3. Check
    Zn + 2H⁺ → Zn²⁺ + H₂
    Each side has 1 Zn, 2 H and a total charge of +2.
  4. Put back the ions that do not change
    Zn + 2HCl → ZnCl₂ + H₂
Who gives, who takes

Oxidising and reducing agents

  • Zn 0 → +2Zn to Zn²⁺: oxidised
  • H +1 → 0H⁺ to H₂: reduced
  • H⁺oxidising agent, gains electrons
  • Znreducing agent, loses electrons
Questions

Zn and HCl: quick answers

What is the balanced equation for zinc and hydrochloric acid?

Zn + 2HCl → ZnCl₂ + H₂. In ionic form: Zn + 2H⁺ → Zn²⁺ + H₂.

Which is the oxidising agent and which is the reducing agent?

Zn goes from 0 to +2 and H goes from +1 to 0. H⁺ is the oxidising agent (it is reduced) and Zn is the reducing agent (it is oxidised).

How many electrons are transferred?

2 electrons pass from Zn to H⁺ in the balanced equation as written.

Balance your own equation