Numford
Photoelectric

Energy of a photon from its wavelength

A photon of 500 nm light has E = hc / λ = 3.98 × 10⁻¹⁹ J = 2.49 eV. Its frequency is c / λ = 6.0 × 10¹⁴ Hz.

Photoelectric effect

Pick a metal and a colour of light. Each photon carries hν; it frees an electron only if hν is more than the work function φ. Brighter light means more photons, not bigger ones. Values use h = 6.63 × 10⁻³⁴ J s and e = 1.6 × 10⁻¹⁹ C.

Metal
Light
Photon energy2.49 eV3.98 × 10⁻¹⁹ J
Threshold5.16 × 10¹⁴ Hzλ₀ = 581 nm
K max0.35 eVfastest at 3.49 × 10⁵ m/s
Stopping potential0.35 Vstops even the fastest
Photons per second5.0 × 10¹⁵at 2 mW

Cs plate in light of 500 nm: electrons leave with up to 0.35 eV.

2.557.5-2ν (10¹⁴ Hz)K max (eV)ν₀ = 5.16-φ = -2.14 eVslope h
K max against ν
-10123V (volt)Current2 mW1 mW-V₀
Current against voltage
Show the working
  1. ν = c / λ = 3 × 10⁸ / (500 × 10⁻⁹) = 6.0 × 10¹⁴ Hz
  2. E = hν = 6.63 × 10⁻³⁴ × 6.0 × 10¹⁴ = 3.98 × 10⁻¹⁹ J = 3.98 × 10⁻¹⁹ / 1.6 × 10⁻¹⁹ = 2.49 eV
  3. ν₀ = φ / h = 2.14 × 1.6 × 10⁻¹⁹ / 6.63 × 10⁻³⁴ = 5.16 × 10¹⁴ Hz, so λ₀ = c / ν₀ = 581 nm
  4. K max = hν - φ = 2.486 - 2.14 = 0.35 eV
  5. eV₀ = K max, so V₀ = 0.35 V
  6. v max = √(2K / m) = √(2 × 5.54 × 10⁻²⁰ / 9.11 × 10⁻³¹) = 3.49 × 10⁵ m/s
  7. Photons per second = P / E = 2.0 × 10⁻³ W / 3.98 × 10⁻¹⁹ J = 5.0 × 10¹⁵
Working

Step by step

  1. ν = c / λ = 3 × 10⁸ / (500 × 10⁻⁹) = 6.0 × 10¹⁴ Hz
  2. E = hν = 6.63 × 10⁻³⁴ × 6.0 × 10¹⁴ = 3.98 × 10⁻¹⁹ J = 3.98 × 10⁻¹⁹ / 1.6 × 10⁻¹⁹ = 2.49 eV
  3. ν₀ = φ / h = 2.14 × 1.6 × 10⁻¹⁹ / 6.63 × 10⁻³⁴ = 5.16 × 10¹⁴ Hz, so λ₀ = c / ν₀ = 581 nm
  4. K max = hν - φ = 2.486 - 2.14 = 0.35 eV
  5. eV₀ = K max, so V₀ = 0.35 V
  6. v max = √(2K / m) = √(2 × 5.54 × 10⁻²⁰ / 9.11 × 10⁻³¹) = 3.49 × 10⁵ m/s
  7. Photons per second = P / E = 2.0 × 10⁻³ W / 3.98 × 10⁻¹⁹ J = 5.0 × 10¹⁵
Across the spectrum

Photon energy by colour

WavelengthFrequencyEnergy (J)Energy (eV)
400 nm7.5 × 10¹⁴ Hz4.97 × 10⁻¹⁹ J3.11 eV
450 nm6.67 × 10¹⁴ Hz4.42 × 10⁻¹⁹ J2.76 eV
500 nm6.0 × 10¹⁴ Hz3.98 × 10⁻¹⁹ J2.49 eV
550 nm5.45 × 10¹⁴ Hz3.62 × 10⁻¹⁹ J2.26 eV
600 nm5.0 × 10¹⁴ Hz3.31 × 10⁻¹⁹ J2.07 eV
650 nm4.62 × 10¹⁴ Hz3.06 × 10⁻¹⁹ J1.91 eV
700 nm4.29 × 10¹⁴ Hz2.84 × 10⁻¹⁹ J1.78 eV
Derivation

Why it works

  1. Light arrives in packets, photons, each of energy E = hν.
  2. One photon is absorbed by one electron, all at once, so there is no delay however dim the light.
  3. The electron must spend at least the work function φ to leave the metal.
  4. The fastest electrons keep the rest: K max = hν - φ. This is Einstein's photoelectric equation.
  5. A retarding voltage V₀ stops even these, so eV₀ = K max. When hν = φ, K max = 0: that frequency is the threshold ν₀ = φ / h.
Questions

Photon energy from wavelength: quick answers

How do you find the energy of a photon from its wavelength?

E = hc / λ, with h = 6.63 × 10⁻³⁴ J s and c = 3 × 10⁸ m/s and λ in metres. Divide by 1.6 × 10⁻¹⁹ to get electron volts.

Which has more energy, a red photon or a violet one?

Violet. E = hc / λ, so the shorter wavelength carries more energy: about 3.1 eV at 400 nm against 1.8 eV at 700 nm.

Can 500 nm light free electrons from caesium?

Yes. 2.49 eV is more than caesium's work function of 2.14 eV, so electrons leave with up to 0.35 eV.

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