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Lewis structure

Lewis structure of C₂H₆

14 valence electrons. One C-C single bond and three C-H single bonds, with no lone pair on C.

HHHCCHHH
  • C
  • H

C₂H₆Ethane

Tetrahedral

AB₄: 4 bond pairs, no lone pairs on each C

  • Hybridisationsp³
  • Bond angleabout 109.5°
  • Polaritynon-polar

Lewis structure

14 valence electrons
CCHHHHHH

Formal charges: none

Why this shape

  1. Each C has 4 valence electrons. It uses four in one single bond to C and three single bonds to H, so none are left over.
  2. Steric number = four sigma bonds + no lone pairs = 4, so each C is sp³ hybridised.
  3. Four electron pairs point to the corners of a tetrahedron (tetrahedral electron geometry). With no lone pairs the atoms take the same shape: tetrahedral.
  4. All the bond pairs repel each other equally, so the angle is the ideal about 109.5°.
  5. Each end is a tetrahedron of C-H bonds and the two ends match, so the bond dipoles cancel.
Working

How to draw it

  1. Count the valence electrons: 2 × C 4 + 6 × H 1 = 14 valence electrons, 7 pairs.
  2. Join the atoms with single bonds: the C atoms to each other and the H atoms around them.
  3. Give each outer atom lone pairs until it has an octet (H needs only two electrons), then put any electrons left over on the central atom.
  4. Result: one C-C single bond and three C-H single bonds, with no lone pair on C.
  5. Formal charge = valence electrons − lone pair electrons − number of bonds. Here: none.

Class 11, Chapter 4 Chemical Bonding and Molecular Structure.

Questions

Lewis structure of C2H6: quick answers

How many valence electrons are in C2H6?

2 × C 4 + 6 × H 1 = 14 valence electrons, 7 pairs.

What are the formal charges in the Lewis structure of C2H6?

Every atom has a formal charge of zero.

How many lone pairs are in the Lewis structure of C2H6?

0 in all, none on the central C.

Try any molecule