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Lewis structure

Lewis structure of NH₄⁺

8 valence electrons. Four N-H single bonds, with no lone pair on N.

HHNHH
  • N
  • H

NH₄⁺Ammonium ion

Tetrahedral

AB₄: 4 bond pairs, no lone pairs

  • Hybridisationsp³
  • Bond angle109.5°
  • Polarityion, charge +1

Lewis structure

8 valence electrons
NHHHH+

Formal charges: N +1

Why this shape

  1. N has 5 valence electrons. In the Lewis structure it makes four single bonds to H and keeps no lone pair, which leaves it a formal charge of +1.
  2. Steric number = four sigma bonds + no lone pairs = 4, so N is sp³ hybridised.
  3. Four electron pairs point to the corners of a tetrahedron (tetrahedral electron geometry). With no lone pairs the atoms take the same shape: tetrahedral.
  4. All the bond pairs repel each other equally, so the angle is the ideal 109.5°.
  5. NH₄⁺ is an ion with an overall charge of +1, so it is not described as polar or non-polar.
Working

How to draw it

  1. Count the valence electrons: N 5 + 4 × H 1 − 1 for the ⁺ charge = 8 valence electrons, 4 pairs.
  2. Put N in the middle and join it to the four outer atoms with single bonds.
  3. Give each outer atom lone pairs until it has an octet (H needs only two electrons), then put any electrons left over on the central atom.
  4. Result: four N-H single bonds, with no lone pair on N.
  5. Formal charge = valence electrons − lone pair electrons − number of bonds. Here: N +1.

Class 11, Chapter 4 Chemical Bonding and Molecular Structure.

Questions

Lewis structure of NH4+: quick answers

How many valence electrons are in NH4+?

N 5 + 4 × H 1 − 1 for the ⁺ charge = 8 valence electrons, 4 pairs.

What are the formal charges in the Lewis structure of NH4+?

N +1; every other atom is zero. Formal charge = valence electrons - lone pair electrons - number of bonds.

How many lone pairs are in the Lewis structure of NH4+?

0 in all, none on the central N.

Try any molecule