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Oxidation number

S in Na₂S₂O₃

S is +2 in sodium thiosulphate, an average.

Oxidation number

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S+2average

The two S atoms in S₂O₃²⁻ are bonded differently, so their own values differ. The rules give the average, +2.

  1. Na is an alkali metal: +1 in its compounds.
  2. Oxygen is −2 in most compounds.
  3. The oxidation numbers add up to the charge, 0: 2(+1) + 3(−2) + 2x = 0.
  4. 2x = +4, so x = +2.
Rule steps

How to find it

  1. Na is an alkali metal: +1 in its compounds.
  2. Oxygen is −2 in most compounds.
  3. The oxidation numbers add up to the charge, 0: 2(+1) + 3(−2) + 2x = 0.
  4. 2x = +4, so x = +2.

The two S atoms in S₂O₃²⁻ are bonded differently, so their own values differ. The rules give the average, +2.

Every atom

All the oxidation numbers in Na₂S₂O₃

  • Na +12 atoms, alkali metal
  • O −23 atoms, oxygen
  • S +22 atoms, sum rule
Questions

S in Na₂S₂O₃: quick answers

What is the oxidation number of S in Na₂S₂O₃?

S in Na₂S₂O₃ (sodium thiosulphate) is +2, an average over its atoms. The two S atoms in S₂O₃²⁻ are bonded differently, so their own values differ. The rules give the average, +2.

How do you find the oxidation number of S in Na₂S₂O₃?

Na is an alkali metal: +1 in its compounds. Oxygen is −2 in most compounds. The oxidation numbers add up to the charge, 0: 2(+1) + 3(−2) + 2x = 0. 2x = +4, so x = +2.

What are the oxidation numbers of the other atoms in Na₂S₂O₃?

Na +1, O −2. Together with S at +2 they add up to the charge of the compound, 0.

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