Numford
Copper and nitric acid

Balance Cu + HNO₃ → Cu(NO₃)₂ + NO₂ + H₂O

Cu(s) + 4 HNO₃(aq) → Cu(NO₃)₂(aq) + 2 NO₂(g) + 2 H₂O(l)

  • Redox reaction
  • 1 : 4 : 1 : 2 : 2 coefficients

Balance an equation

Arrow. Type -> or =. Subscripts. Plain digits: H2SO4, Ca(OH)2, CuSO4.5H2O. Charges. Fe3+, OH-, SO4 2-, and e- for an electron. States. (s), (l), (g) and (aq) are kept. Coefficients you type are checked.

Cu(s)+4HNO₃(aq)→Cu(NO₃)₂(aq)+2NO₂(g)+2H₂O(l)

Balanced

Atoms on each side

AtomAs writtenleft : rightBalancedleft : right
Cu1:11:1
H1:24:4
N1:34:4
O3:912:12

Check atoms

How to balance it
Working

How to balance it, step by step

  1. Count the atoms of each element on both sides, as written.
  2. This one needs two coefficients at once, so write a letter for each: a Cu, b HNO₃, c Cu(NO₃)₂, d NO₂, e H₂O.
  3. Cu: a = c
  4. H: b = 2e
  5. N: b = 2c + d
  6. O: 3b = 6c + 2d + e
  7. Solve, keeping the smallest whole numbers: a = 1, b = 4, c = 1, d = 2, e = 2.
  8. Check: Cu 1 = 1, H 4 = 4, N 4 = 4, O 12 = 12. Balanced.
The reaction

What happens

It is a redox reaction: one substance is oxidised while another is reduced. Concentrated nitric acid oxidises copper, giving a blue solution of copper nitrate and brown fumes of nitrogen dioxide. Copper does not give hydrogen with nitric acid.

Questions

Copper and nitric acid: quick answers

What is the balanced equation for copper and nitric acid?

Cu(s) + 4 HNO₃(aq) → Cu(NO₃)₂(aq) + 2 NO₂(g) + 2 H₂O(l). The coefficients are 1, 4, 1, 2 and 2. Each side then has 1 Cu, 4 H, 4 N and 12 O.

What type of reaction is copper and nitric acid?

It is a redox reaction: one substance is oxidised while another is reduced. Concentrated nitric acid oxidises copper, giving a blue solution of copper nitrate and brown fumes of nitrogen dioxide. Copper does not give hydrogen with nitric acid.

How do you balance Cu + HNO₃ → Cu(NO₃)₂ + NO₂ + H₂O?

This one needs two coefficients at once, so write a letter for each: a Cu, b HNO₃, c Cu(NO₃)₂, d NO₂, e H₂O. Cu: a = c H: b = 2e N: b = 2c + d O: 3b = 6c + 2d + e Solve, keeping the smallest whole numbers: a = 1, b = 4, c = 1, d = 2, e = 2. Never change a subscript, because that would change the substance.

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