Numford
Ion configuration

Fe³⁺ ion

[Ar] 3d⁵. 5 unpaired electrons, paramagnetic.

Element or ion

Type a symbol, a name or an atomic number, add a charge such as Fe3+ or Cl-, or tap an element in the table. Orbitals fill from m = −l up, spin +½ first.

+3
H1He2Li3Be4B5C6N7O8F9Ne10Na11Mg12Al13Si14P15S16Cl17Ar18K19Ca20Sc21Ti22V23Cr24Mn25Fe26Co27Ni28Cu29Zn30Ga31Ge32As33Se34Br35Kr36Rb37Sr38Y39Zr40Nb41Mo42Tc43Ru44Rh45Pd46Ag47Cd48In49Sn50Sb51Te52I53Xe54Cs55Ba56Hf72Ta73W74Re75Os76Ir77Pt78Au79Hg80Tl81Pb82Bi83Po84At85Rn86

Fe3+Iron ion, 23 electrons

[Ar] 3d5

In full: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵. Fe loses 4s² then 3d¹

Fe loses 4s² then 3d¹

[Ar]3d4s (empty)
  • Blockd block
  • Period4
  • Group8
  • Outer shell13
  • Unpaired5
  • MagneticPara

Last electron 3d

  • n3shell
  • l2d subshell
  • m+2orbital
  • s+½spin up
Working

Step by step

  1. Iron has 26 electrons: [Ar] 3d⁶ 4s².
  2. The ion has 3 fewer, 23 electrons. Remove them from the highest n first.
  3. Fe loses 4s² then 3d¹.
  4. Fe³⁺ ion: [Ar] 3d⁵, in full 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵.
At a glance

Fe³⁺ ion: the numbers

Atomic number26
Electrons23
Period4
Group8
Blockd block
Electrons in the outer shell13
Unpaired electrons5
Magneticparamagnetic
Last electron3d: n = 3, l = 2, m = +2, s = +1/2
Questions

Fe³⁺ ion: quick answers

What is the electronic configuration of Fe³⁺?

Fe³⁺ has 23 electrons: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵, or [Ar] 3d⁵. Fe loses 4s² then 3d¹.

How many unpaired electrons are there in Fe³⁺?

Fe³⁺ has 5 unpaired electrons, so it is paramagnetic.

Why does Fe lose its outer electrons first?

Electrons leave from the highest n first. The 4s level fills before 3d, but once 3d holds electrons the 4s electrons are the outermost, so they are lost first.

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